Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
 
Synthesis and Optical Properties of Pyridino End-Capped Oligothiophenes
Yong-Mook HwangJoji OhshitaTomonobu MizumoHiroto YoshidaYoshihito KunugiTakashi Sugioka
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2011 Volume 84 Issue 11 Pages 1243-1247

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Abstract

Oligothiophenes end-capped with fused pyridino units were synthesized by means of the Stille coupling and their optical properties were studied. These compounds show absorption maxima and edges at 324–374 nm and 3.10–2.76 eV, respectively, depending on the oligothiophene chain lengths. DFT calculations indicate that both the HOMO and LUMO levels are lowered by the introduction of the pyridino units.

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© 2011 The Chemical Society of Japan
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