Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Reaction Pathways and Dynamics Effects for Ionizations of Vinyl Diazonium Ions
Tomoyuki MizutaniMasaru JingujiHiroshi Yamataka
Author information

2012 Volume 85 Issue 10 Pages 1112-1119


The denitrogenation reactions of fifteen differently substituted vinyl diazonium (ethenediazonium) ions were examined by MO method at MP2/6-31G*. The parent vinyl diazonium ion (1, CH2=CH–N2+) was shown to initially give the H-bridged cation via the anti-H migration transition state (TS) or the syn-H migration TS. The relative barrier for the two TSs is very small, being 1.0 kcal mol−1 favoring the anti-H migration TS in free energy. The primary open cation is located on a very shallow minimum, and is 4.4 kcal mol−1 less stable than the bridged cation in free energy. The reactions of Me- and Ph-substituted vinyl diazonium ions showed characteristic features depending on the substituent. Molecular dynamics simulations for the reactions of 1 revealed that trajectories from the reactant state mostly gave the bridged cation as expected from the MO result, but there were trajectories that directly led to the open cation without H-participation, a clear manifestation of a dynamics effect. A dynamics effect on the relative population of the bridged versus the open cation is also presented.

Information related to the author

This article cannot obtain the latest cited-by information.

© 2012 The Chemical Society of Japan
Previous article Next article