Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
BCSJ Award Article
Effect of Charge of a Matrix Polymer on the Electronic States of Single-Walled Carbon Nanotubes
Yasuhiko HiranaYasuro NiidomeNaotoshi Nakashima
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2012 Volume 85 Issue 12 Pages 1262-1267

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Abstract

The determination of electronic states of single-walled carbon nanotubes (SWNTs) has been a central issue in science and nanotechnology of carbon nanotubes. Previously, we reported the electronic states of (n,m)SWNTs that were embedded in an anionic polymer, carboxymethylcellulose sodium salt (CMC). It is important to reveal how the electronic properties of individual (n,m)SWNTs are affected by the surrounding microenvironment. In this study, we focused on the effect of charge of the SWNT solubilizers. We used a cationic polymer, hydroxyethylcellulose ethoxylate (quaternized) (HEQ) as the SWNT solubilizer in place of CMC, and the isolated (n,m)SWNTs were embedded in a film of HEQ (matrix polymer) on an electrode. We found that the charge of HEQ virtually does not affect the electronic parameters, i.e., oxidation/reduction potentials, Fermi levels, and band gaps of the (n,m)SWNTs, indicating that the presented electronic parameters are the parameters of the intrinsic (n,m)SWNTs.

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© 2012 The Chemical Society of Japan
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