Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Supramolecular Structures of Inclusion Complexes of Cyclic Porphyrin Dimers and [6,6]-Phenyl-C61-Butyric Acid Methyl Ester (PCBM)
Hirofumi NobukuniTakuya KamimuraHidemitsu UnoYuichi ShimazakiYoshinori NarutaFumito Tani
Author information

2012 Volume 85 Issue 8 Pages 862-868


Cyclic nickel and free-base porphyrin dimers (Ni2-CPDPy and H4-CPDPy) include [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) both in solution and in the crystals. In the crystal packing of the inclusion complex of Ni2-CPDPy and PCBM, a nanotubular structure is constructed through the self-assembly of the porphyrin moiety. The PCBM molecules are linearly arranged in the inner channel of the nanotube to give a supramolecular peapod. On the other hand, in the crystal of the inclusion complex of H4-CPDPy and PCBM, a dimeric structure of the PCBM molecules is formed through π–π interaction between their phenyl groups.

Information related to the author

This article cannot obtain the latest cited-by information.

© 2012 The Chemical Society of Japan
Previous article Next article