Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
 
New Strongly Correlated One-Dimensional Organic Semiconductor (ChTM-TTP)2Ag(CN)2
Tadashi KawamotoMinoru AshizawaTakehiko Mori
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2013 Volume 86 Issue 4 Pages 526-528

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Abstract

Crystal structure, transport, and magnetic properties of a new organic conductor (ChTM-TTP)2Ag(CN)2, where ChTM-TTP is 2-[4,5-(1,2-cyclohexylenedithio)-1,3-dithiol-2-ylidene]-5-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-1,3,4,6-tetrathiapentalene, have been studied. Although the crystal structure is similar to metallic ChTM-TTP conductors, the present compound is a paramagnetic semiconductor even at room temperature, indicating strongly electron correlation.

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© 2013 The Chemical Society of Japan
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