Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
 
Stereospecific Aerobic Oxidative Dehydrocoupling of P(O)–H Bonds with Amines Catalyzed by Copper
Yongbo ZhouJia YangTieqiao ChenShuang-Feng YinDaoqing HanLi-Biao Han
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2014 Volume 87 Issue 3 Pages 400-402

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Abstract

Copper-catalyzed stereospecific oxidative dehydrocouplings of P(O)–H bonds with amines under air took place efficiently at room temperature to afford the corresponding amidophosphorus compounds in high yields. Mechanistic studies showed that this dehydrocoupling reaction proceeded stereospecifically with inversion of stereochemistry at phosphorus.

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© 2014 The Chemical Society of Japan
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