2014 Volume 87 Issue 3 Pages 417-419
Supramolecular cation salt of adamantane rotator with a dithiolene complex, (fluoroadamantylammonium+)(crown-6)[Ni(dmit)2]− (1) was synthesized. The fluorine atom of the adamantane unit showed a large thermal factor elongated latitudinally, suggesting molecular rotation in the solid state. Crystal 1 exhibited a large dielectric response by applying an AC field along the a axis.
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