Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
 
Crystal Structure and Physical Properties of a Dithiolene Complex Crystal with Adamantane Supramolecular Rotator
Yin-Nan YanKazuya KuboShin-ichiro NoroTomoyuki AkutagawaTakayoshi Nakamura
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2014 Volume 87 Issue 3 Pages 417-419

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Abstract

Supramolecular cation salt of adamantane rotator with a dithiolene complex, (fluoroadamantylammonium+)([18]crown-6)[Ni(dmit)2] (1) was synthesized. The fluorine atom of the adamantane unit showed a large thermal factor elongated latitudinally, suggesting molecular rotation in the solid state. Crystal 1 exhibited a large dielectric response by applying an AC field along the a axis.

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© 2014 The Chemical Society of Japan
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