Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
 
Photoinduced Regio- and Stereoselective Introduction of Phenylchalcogeno Moieties to Ethynylferrocene
Akihiro NomotoSatoko HayashiTakuya FujiyamaTakuma IkedaKiichi HirataJun TohomaKiyomi KakiuchiWaro NakanishiAkiya Ogawa
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Volume 87 (2014) Issue 4 Pages 550-552

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Abstract

Upon photoirradiation, diphenyl diselenide and diphenyl ditelluride reacted with ethynylferrocene to afford the corresponding bischalcogenated vinylferrocenes. Regio- and stereoselectivities were determined by X-ray crystal analysis, and redox properties were investigated by cyclic voltammetry.

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© 2014 The Chemical Society of Japan
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