Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
 
Fibrous Crystals of E,E-1,4-Bis(3,5-ditrifluoromethylstyryl)benzene with High Emission Ability
Hiroyuki Mochizuki
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2018 Volume 91 Issue 3 Pages 444-446

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Abstract

E,E-1,4-Bis(2,4-ditrifluoromethylstyryl)benzene (d24CF3) and E,E-1,4-bis(3,5-ditrifluoromethylstyryl)benzene (d35CF3) were synthesized. The d35CF3 crystals grown from solution displayed a unique fibrous form and emitted propagated fluorescence, and a d35CF3 film demonstrated a very low ionization potential of −6.7 eV. Meanwhile, d24CF3 crystals exhibited aggregation-induced emission.

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© 2018 The Chemical Society of Japan
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