Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Reproducible Ionization of Gold Nanospheres and Nanostars in Gelatin Sections
Tomoki NishiDaiki MukoJanice B. RaborYasuro Niidome
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2020 Volume 93 Issue 1 Pages 58-64


Gold nanospheres were dispersed in gelatin sections (10–100 µm thickness) and their laser desorption/ionization (LDI) efficiencies of gold ions (Au+, Au2+, Au3+) under pulsed-laser irradiation were examined. The mass signal intensities were linear to the surface densities ranging from 6 × 104 to 6 × 106 particles/mm2. When the thickness of the sections was thinner than or equal to 50 µm, the LDI efficiency of gold nanospheres was independent of the thickness. Thus, the mass intensity was dependent on the surface densities of gold nanospheres in the gelatin sections. It was also found that the LDI efficiencies were affected by the concentration of gelatin solutions. Based on the high reproducibility of mass signals obtained from gelatin sections, the LDI efficiencies of star-shaped gold nanoparticles (gold nanostars) were also evaluated. It was found that the nanostars showed higher LDI efficiencies than gold nanospheres, but the enhancement was not more than 25%.

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© 2020 The Chemical Society of Japan
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