Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
On the Silver Oxide Positive of the Alkaline Accumulator. I
Kyôji Kinoshita
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1937 Volume 12 Issue 4 Pages 164-172

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Abstract

(1) A cell was constructed from the silver positive and iron negative in KOH solution, and the charge and discharge curves of the positive were examined.
(2) It was known that the discharge curve runs in two steps in general, which can be interpreted by assuming that there occurs the following consecutive chemical reactions.
Ag_2O_2→Ag_2O→2Ag
(3) The chemical analysis of the active material of charged silver positive supports the above consideration.
(4) The coefficient of utility of the active material of the silver positive is much higher than that of the lead peroxide positive of the lead acid cell.

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