Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Dipole Moments of Benzil and Stilbene Dichloride
Ken-iti Higasi
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1938 Volume 13 Issue 1 Pages 158-166

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Abstract

(1) The dipole moment of benzil was studied in three solvents and its temperature dependence was examined.
(2) The carbon-carbon bond of benzil is not a pure single bond and is probably a hybrid of single and double bonds. This is the result expected from Thiele’s old idea of conjugated system and also from the quantum mechanical resonance.
(3) The dipole moment of α-stilbene dichloride was also studied in benzene and carbon tetrachloride solution. The result was compared with that of ethylene dichloride.

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