Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Concentration Polarization and the Polarographic Current-Time Curve. I. Rate of the Consecutive Reaction Consisting of the Linear Diffusion Process and the Electrode Reaction
Tomihito KambaraIsamu Tachi
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1952 Volume 25 Issue 3 Pages 135-142

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Abstract

The differential equation of linear diffusion was solved with the boundary condition controlled by the chemical kinetics. The result obtained gives the rate of the consecutive reaction consisting of the diffusion process and the electrode process. This theory can explain the course of the polarographic current-time curve very well.

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