Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
On the Acidity of Boric Acid. I. Neutral-Salt Effect Observed by Alkali-titration
Shunsuke Shishido
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1952 Volume 25 Issue 3 Pages 199-202

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Abstract

The acidifying effect of various solutions (CH3OH, C2H4(OH)2, C3H5(OH)3, C6H8(OH)6, their mixture, CH3COCH3, O(CH2CH2)2O, and neutral-salts) is measured by the alkali-titration method, and the simple relation between the hydration energy of neutral-salts and their acidifying effect is found. The consistent explanation for these phenomena is proposed on the view of the nature of the tricovalent and teracovalent bond of boron atom.

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