Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Interaction Polarization of the Hydrogen Bonded Complexes. II
Ko KimuraRyoichi Fujishiro
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1961 Volume 34 Issue 3 Pages 304-308

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Abstract

The dielectric measurements were carried out for benzyl alcohol + α, α′-bipyridyl, benzyl alcohol + triethylamine, phenol + α, α′-bipyridyl and phenol + triethylamine by using benzene as a solvent, and the polarization value for each system was calculated. The additional moments due to complex formation were evaluated, as in the previous paper, from both the polarization data and the spectroscopically determined formation constants. Then the weight of structure III was estimated and correlated with the wave number shift Δν of the OH stretching vibration.

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