1962 Volume 35 Issue 7 Pages 1055-1057
The observed spectra of water of crystallization were compared with those of aluminum chloride hexahydrate and interpreted on the basis of the effects of aluminum-water coördination and hydrogen bonding O–H…O. The wagging and the rocking frequency were both much higher than is usual in water of crystallization. It was proposed that this result, together with other peculiarities, may have some connection with the coördination strength between aluminum and water.
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