Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Infrared Absorption Spectra of Water of Crystallization in Aluminum Sulfate Octodecahydrate Crystals
Itaru Gamo
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1962 Volume 35 Issue 7 Pages 1055-1057

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Abstract

The observed spectra of water of crystallization were compared with those of aluminum chloride hexahydrate and interpreted on the basis of the effects of aluminum-water coördination and hydrogen bonding O–H…O. The wagging and the rocking frequency were both much higher than is usual in water of crystallization. It was proposed that this result, together with other peculiarities, may have some connection with the coördination strength between aluminum and water.

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