Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Infrared Absorption Spectra of Water of Crystallization in Sodium Sulfate Decahydrate Crystals
Itaru Gamo
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1962 Volume 35 Issue 7 Pages 1058-1059

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Abstract

The observed spectra of water of crystallization were interpreted on the basis of the effect of hydrogen bonding. It was proposed that at least two kinds of water molecules exist in the unit cell of the crystal. The corresponding two O–H…O distances were roughly estimated to be 3.01 and 2.58 Å respectively by the use of Glemser’s relationship between the stretching frequency and the hydrogen bond distance.

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