Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
A Selective Phosphorylation by Means of α-Bromocyano acetamides and Trialkyl Phosphites
Tsujiaki HataTeruaki Mukaiyama
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1962 Volume 35 Issue 7 Pages 1106-1109

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Abstract

A method of selective phosphorylation by means of α-bromocyanoacetamides and trialkyl phosphites was devised. In this method, various phosphates, pyrophosphates and phosphoramidate were obtained in excellent yields under mild conditions without isolating the intermediate, enol-phosphate.
The use of dibromocyanoacetamide in place of monobromocyanoacetamide produced the same results, the yields being, however, less.
A new method for the preparation of monobromocyanoacetamide was also described.

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