Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Sterically-hindered Organosilicon Compounds Containing Cyclohexyl Groups. I. Reactions of Organolithium Compounds with Tricyclohexylfluorosilane
Michio Takakusa
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1963 Volume 36 Issue 1 Pages 31-33

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Abstract

The reactions of tricyclohexylflurosilane with n-butyl-, phenyl-, isopropyl- and cyclohexyllithiums in boiling petroleum ether (90∼110°C) were studied, and tricyclohexylbutylsilane and tricyclohexylphenylsilane were prepared (41 and 72%, respectively) for the first time. A secondary alkyl group can not be bonded to the silicon of tricyclohexylsilyl group even under these drastic conditions.

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