Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Decomposition of Peroxybenzoic Acid in Solution. V. Decomposition of Peroxybenzoic Acid and of Benzoyl Peroxide in Binary Mixtures of Carbon Tetrachloride with Cyclohexane, Toluene, or Diethyl Ether
Katsumi TokumaruOsamu Simamura
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1963 Volume 36 Issue 1 Pages 76-79

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Abstract

Decompositions of peroxybenzoic acid and of benzoyl peroxide were carried out in binary mixtures of carbon tetrachloride with cyclo-hexane, toluene or diethyl ether. The results of the product study strongly support the radical mechanism established previously and show that the oxygen to oxygen bond of peroxybenzoic acid is attacked by radicals more readily than that of benzoyl peroxide, but even peroxybenzoic acid is hardly attacked by the trichloromethyl radical.

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