Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Pyrolysis of Acid Amides. III. Pyrolysis of Cyanoacetamides and 2-Phenylacetamides
Teruaki MukaiyamaHisashi TakeiYasuo Koma
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1963 Volume 36 Issue 1 Pages 95-99

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Abstract

The pyrolyses of cyanoacetamides, 2-phenylacetanilide, 2,2-diphenylacetanilide and 2,2,2-triphenylacetanilide have been studied. The pyrolysis of cyanoacetamides gave the corresponding isocyanates and acetonitrile. On the other hand, the pyrolysis of 2-phenylacetanilide and 2,2-diphenylacetanilide gave a small amount of phenyl isocyanate, along with various byproducts. The pyrolysis of 2,2,2-triphenyl-acetanilide, however, against expectation, did not give isocyanate; only a tarry product resulted.

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