Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Infrared Spectra and Rotational Isomerism of Some Long-chain n-Alkoxy Ethanols
T. K. K. SrinivasanC. I. JoseA. B. Biswas
Author information
JOURNALS FREE ACCESS

1964 Volume 37 Issue 12 Pages 1770-1775

Details
Abstract

The infrared spectra of n-alkoxy ethanols CH3(CH2)nO-CH2-CH2-OH with n=13,15,17,19 and 21 have been obtained in the solid and liquid states as well as in solution. From a study of the CH2 rocking modes of the (O–CH2-CH2-O) group at 893 cm−1 and 864 cm−1 during liquid-solid transformation and from the solution spectra in the hydroxyl-stretching region, it has been shown that this group exists predominantly in a gauche configuration in liquids or in solution, while both gauche and trans configurations are present in the solid state.

Information related to the author

This article cannot obtain the latest cited-by information.

© The Chemical Society of Japan
Previous article Next article
feedback
Top