Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Heats of Mixing for Binary Mixtures. The Energy of Hydrogen Bonding between Alcohol and Ketone Molecules
Sachio MurakamiKazuo AmayaRyoichi Fujishiro
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1964 Volume 37 Issue 12 Pages 1776-1780

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Abstract

A microcalorimeter of the twin type has been constructed, one which is operated semiautomatically. Using this apparatus, the heats of mixing for alcohol-ketone, alcohol-hexane, and ketone-hexane solutions have been measured. From these heats of mixing, the hydrogen bond energy of the O–H…O= type has been estimated to be about 4kcal. by means of the thermochemical cycle.

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