Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Electronic Spectra of Aniline and N-Methylaniline Adsorbed on Aluminum Chloride. II. The Theoretical Treatment
Hiroyasu SatoSaburo NagakuraKozo Hirota
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1965 Volume 38 Issue 10 Pages 1730-1733

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Abstract

The electronic spectra of aniline and N-methylaniline adsorbed on aluminum chloride have been examined by the LCMO method and have been compared with those of gaseous aniline, N-methylaniline, toluene and ethylbenzene. All of these molecules can be treated by the intramolecular charge-transfer model. In order for us to be able to interpret the spectra from the LCMO point of view, the ionization potential of the electron donating group in aniline and N-methylaniline molecules should rise upon adsorption on aluminum chloride.

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