Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Heat Capacity and the Entropy of Transition of Würster’s Blue Perchlorate
Hideaki ChiharaMinoru NakamuraSyûzô Seki
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1965 Volume 38 Issue 10 Pages 1776-1778

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Abstract

The heat capacity of Würster’s Blue perchlorate (N,N,N′,N′-tetramethyl-p-phenylene-diamine perchlorate) has been measured between 66 and 200°K. A phase transition occurs at 189.9°K with its tail extending down to about 160°K. The transition is probably of the first order. The heat and the entropy of the transition are 408.6±4.5 cal./mol. and 2.19±0.02 cal./deg.mol. respectively. The magnetic susceptibility of the specimen at room temperature indicates that the paramagnetic spin density is 100±3%. The experimental results have been compared with current theories, and it has been inferred that some unknown structural changes are involved in the phase transition.

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