Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Some Acetylene Complexes of Vanadium
Ryuichiro TsumuraNobue Hagihara
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1965 Volume 38 Issue 11 Pages 1901-1905

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Abstract

Some acetylene complexes of vanadium of the π-C5H5(RC2H)V(CO)2 (R=H, n-C3H7, n-C4H9 and (CH3)3C) and π-C5H5(PhC2Ph)V-(PPh3)(CO) types have been prepared by the photochemical reaction of the corresponding acetylene with π-cyclopentadienyl-vanadium tetracarbonyl and its phosphine derivative irespectively. It has been proposed, on the basis of their infrared and nuclear magnetic resonance spectra, that the acetylene complexes of vanadium have a structure in which the acetylene molecule is bonded via two σ-bondings to a vanadium atom.

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