Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Effect of Hydrogen-Bonding on the g-Value of Diphenyl Nitric Oxide
Takashi KawamuraShoichi MatsunamiTeijiro YonezawaKenichi Fukui
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1965 Volume 38 Issue 11 Pages 1935-1940

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Abstract

The decrease in the g-value of diphenyl nitric oxide in hydrogen-bonding solvents has been examined. This decrease has been analyzed on the basis of Stone’s theory for the g-value of a π-radical. The decrease in the g-value has been shown to be caused mainly by the decrease in the odd-electron density on the oxygen atom and the increase in the energy difference between the odd-electron and lone-pair orbitals. We have also attempted to estimate the blue shift of the n* transition from the g-value.

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