Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Reactions of Benzoyl Cyanide with Trivalent Phosphorus Compounds
Teruaki MukaiyakaIsao KuwajimaKiyotaka Ohno
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1965 Volume 38 Issue 11 Pages 1954-1957

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Abstract

The reactions of various p-substituted benzoyl cyanides with trivalent phosphorus compounds have been studied. They react with triethyl phosphite to form 2 : 1 adducts which, upon being heated in xylene, decomposed into the corresponding dicyanostilbene oxide and triethyl phosphate. The reaction with tri-n-butylphosphine, on the other hand, gives cis-dicyanostilbene derivatives. These reactions can be explained by a mechanism through similar intermediates.

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