Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Radiation-Induced Addition Reaction of Thiols to Chlorofluoroolefins
Kan InukaiTeruo UedaHiroshige Muramatsu
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1966 Volume 39 Issue 10 Pages 2191-2194

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Abstract

The addition of thiols to chlorofluoroethylenes was carried out under γ-ray irradiation; chlorofluoroethyl alkyl sulfides were thus obtained. Ghlorofluoroethyl alkyl sulfoxides and sulfones were prepared by the oxidation of the sulfides. The dehydrohalogenation of chlorofluoroethyl alkyl sulfides yielded chlorofluorovinyl alkyl sulfides, whose structure indicated that the thiyl radical attacked the difluoromethylene side of the asymmetrical dichlorodifluoroethylene. Chlorofluorovinyl sulfoxides and sulfones were also synthesized from the sulfides by oxidation with hydrogen peroxide.

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