Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Studies on Geometric Isomerism by Nuclear Magnetic Resonance. IV. Structure of α-Cyano-β-amino-β-alkylacrylic Esters
Toshio HayashiIsaburo HoriHideo BabaHiroshi Midorikawa
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1967 Volume 40 Issue 9 Pages 2160-2163

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Abstract

The NMR spectra of α-cyano-β-amino-β-alkylacrylic esters prepared from α-cyano-β-methoxy-β-alkylacrylic esters and simple amines have been studied. It has been found that these aminoesters, in a variety of solvents, are all present in an intramolecular hydrogen-bonded enamine form with a chelate ring.

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