Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Structure of Meisenheimer Complex as Determined by X-ray Crystal Analysis
Hideo UedaNoriyoshi SakabeJiro TanakaAkio Furusaki
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1968 Volume 41 Issue 12 Pages 2866-2871


The structure of the Meisenheimer complex has been determined by the X-ray method. The complex is characterized by a symmetrical structure, in which the two methoxyl groups are nearly equivalent to each other. The results showed a peculiar shape of the reaction intermediate, the substituted carbon atom is transformed into a tetrahedral shape, while the planarity of the whole molecule is kept with an increased conjugation between the nitro group and the ring system.

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