Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Synthesis of 4,5-Di- and 1,4,5-Trisubstituted Imidazole Derivatives from 4,5-Dicyanoimidazole
Yoshitaka YamadaIzumi KumashiroTadao Takenishi
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1968 Volume 41 Issue 5 Pages 1237-1240

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Abstract

The chemical reactivities and the synthesis of various derivatives of 4,5-dicyanoimidazole formed by heating a solution of hydrogen cyanide in liquid ammonia were studied, as were the partial hydrolysis, hydrogenation, and addition reaction of cyano groups and the alkylation, cyano-ethylation, and vinylation of the imidazole ring. From these experiments, a few new compounds were synthesized, which had been expected as intermediates of polymers containing imidazole rings.

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