Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Polar Conjugative Effect of Aryldithia Group on the Dissociation and Ultraviolet Spectra of Substituted Phenols
Shigeru OaeMasakuni Yoshihara
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1968 Volume 41 Issue 9 Pages 2082-2086

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Abstract

A few substituted aryldithiaphenols have been synthesized and their acid dissociations, NMR chemical shifts and UV spectra have been determined. The relatively stronger acidic nature of p-aryldithiaphenols over that of the meta-isomers is interpreted as being caused by the 3d-orbital resonance effect of the aryldithia group.

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