Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Radical Conversions in γ-Irradiated 3-Methylpentane-Isobutene Systems
Kozo TsujiSeizo Okamura
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1969 Volume 42 Issue 10 Pages 2827-2830

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Abstract

Radical conversions in γ-irradiated 3-methylpentane-isobutene systems were observed by means of the electron spin resonance method after keeping the sample at −196°C for a few days, or by subjecting it to ultraviolet irradiation. One of the changes was caused by hydrogen atom abstraction from neighboring molecules by original free radicals. The other change was attributed to dissociation of the free radicals from 3-methylpentane by ultraviolet irradiation.

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