Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Separation and Identification of Chlorocomplexes of Technetium(IV) formed in Hydrochloric Acid Solutions
Yoshihiko Kanchiku
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1969 Volume 42 Issue 10 Pages 2831-2835

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Abstract

The chemical behavior of TcCl62− in HCl solutions of different concentrations has been investigated. It was confirmed that TcCl62− is sensitive to ultraviolet and visual light, giving a series of aquated species the quantities of which depend on the HCl concentration. Those technetium(IV) chlorocomplexes were isolated by means of ion-exchange and paper electro-phoresis, and the composition of each species was determined by measuring the Cl/Tc ratio and the charge per species. The absorption spectra of isolated species were also measured.

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