Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Absorption Spectra and Circular Dichroisms of Metal Complexes. IV. Dichloro-diamine Type Complexes of Platinum(II) and Palladium(II)
Haruko ItoJunnosuke FujitaKazuo Saito
Author information
JOURNALS FREE ACCESS

1969 Volume 42 Issue 10 Pages 2863-2869

Details
Abstract

Absorption (AB) spectra of dichloro(l-tetrahydrogenpropylenediaminetetraacetato)platinum-(II) and palladium(II) and dichloro(d-hydrogendiaminopropionato)platinum(II) and palladium(II) were interpreted on the basis of a comparison of their circular dichroism (CD) spectra with those of dichloro(l-propylenediamine)platinum(II) and palladium(II). The d-d bands of edtaH4 and l-pdtaH4 complexes shifted to longer wavelength as compared with those of l-pn complexes. The shift was discussed, based on the effects of the weaker ligand field strength and apical interaction of the acetato groups of these ligands.

Information related to the author

This article cannot obtain the latest cited-by information.

© The Chemical Society of Japan
Previous article Next article
feedback
Top