Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Absorption Spectra and Circular Dichroisms of Metal Complexes. IV. Dichloro-diamine Type Complexes of Platinum(II) and Palladium(II)
Haruko ItoJunnosuke FujitaKazuo Saito
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1969 Volume 42 Issue 10 Pages 2863-2869


Absorption (AB) spectra of dichloro(l-tetrahydrogenpropylenediaminetetraacetato)platinum-(II) and palladium(II) and dichloro(d-hydrogendiaminopropionato)platinum(II) and palladium(II) were interpreted on the basis of a comparison of their circular dichroism (CD) spectra with those of dichloro(l-propylenediamine)platinum(II) and palladium(II). The d-d bands of edtaH4 and l-pdtaH4 complexes shifted to longer wavelength as compared with those of l-pn complexes. The shift was discussed, based on the effects of the weaker ligand field strength and apical interaction of the acetato groups of these ligands.

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