Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Reaction of Titanium Tetrahalides with Phenylhydrazones
R. C. AggarwalS. K. Singh
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1969 Volume 42 Issue 10 Pages 2878-2881

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Abstract

Titanium tetrafluoride reacts with benzaldehyde phenylhydrazone to yield 1:1 adduct and with benzophenone phenylhydrazone 1:2 as well as 2:1 adducts, while other tetrahalides form 1:1 adducts with both the phenylhydrazones. All these complexes are coloured and stable at room temperature. The infrared spectral studies of phenylhydrazones and their titanium (IV) complexes have been made in the 4000–200 cm−1 region.

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