1969 Volume 42 Issue 10 Pages 2899-2903
The alkaline hydrolysis of substituted phenyl benzenethiolsulfinates has been kinetically investigated. The rates were correlated with the second order kinetic equation, first order with respect to each of the hydroxide and the ester concentration. The second order rate constant for the unsubstituted ester was found to be 3.17×103 l/mol sec (water, 30°C). The Hammett ρ values were found to be ρX,Y=H=2.4 and ρY,X=H=1.6 for (Remark: Graphics omitted.) respectively.
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