Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Studies on s-Triazines. II. Cotrimerization of Trichloroacetonitrile with Thiocyanates
Ko WakabayashiMasaru TsunodaYasushi Suzuki
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1969 Volume 42 Issue 10 Pages 2931-2937

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Abstract

2-Substituted thio-4,6-bis(trichloromethyl)-s-triazmes, a new class of s-triazine derivatives, were obtained by the cotrimerization of CCl3CN with a wide variety of thiocyanates. Generally, the reaction proceeded smoothly at ordinary pressure in the presence of hydrogen chloride or the combined catalyst, Friedel-Crafts catalyst-hydrogen chloride.

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