Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The “Circular Dichroism-sensitive Band” in the Optical Absorption of the Lanthanide(III) Complexes with Some Optically Active Ligands
Seizo MisumiSigeo KidaToshiyuki IsobeYuzo NishidaHaruko Furuta
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1969 Volume 42 Issue 12 Pages 3433-3437

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Abstract

The circular dichroism and absorption spectra of Pr(III), Nd(III), Sm(III), Dy(III), Ho(III), Er(III) and Tm(III) complexes with some natural amino acids and L-EDDS have been measured at room temperature. The “circular dichroism-sensitive bands” have been observed on the J-bands where magnetic dipole transitions are allowed to some extent. The experimental results are in accordance with the theory proposed previously. The theory can be applied at least for lanthanide(III) complexes.

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