Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Oxygenation-deoxygenation of Cobalt(II) Complexes on Polymers
Akira MisonoSeiichiro KodaYasuzo Uchida
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1969 Volume 42 Issue 12 Pages 3470-3477

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Abstract

Three cobalt(II) complexes, bis-(salicylaldehyde)-ethylenediimine-cobalt(II), bis-(salicylaldimino) cobalt(II), and di-(salicylal)-3,3′-diimino-di-n-propylamine-cobalt(II), were mixed with poly-4-vinylpyridine. These mixtures showed ESR signals which reversively appeared under oxygen. We tried to identify these signals on the basis of the electonic structure, cobalt(III)-O2−1. The oxygenation-deoxygenation rates were also observed and found to obey the Elovich rate equation.

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