Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Reaction of Ethyl Diazoacetate with Cupric Chloride
Takeo SaegusaYoshihiko ItoToyoji ShimizuShiro Kobayashi
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1969 Volume 42 Issue 12 Pages 3535-3538

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Abstract

The reaction of ethyl diazoacetate (1) with CuCl2 was investigated. Ethyl chloroacetate (2), ethyl dichloroacetate (3) and a mixture of ethyl dichloromaleate (4) and ethyl dichlorofumarate (5) were produced. These products were explained by assuming 1-chloro-1-ehtoxycarbonylmethylcopper complexes, (10) and (11). The reactions of 1 with HgCl2 and CoCl2 were examined in detail as reference reactions from the mechanistic view point.

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