Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Anodic Reaction of Acetic Acid in the Presence of Enanthaldehyde, Enanthaldehyde Diethyl Acetal, and 2-Octanone
Akira TakedaSatosi WadaSigeru ToriiYuji Matsui
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1969 Volume 42 Issue 4 Pages 1047-1051

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Abstract

The anodic methylation of enanthaldehyde, enanthaldehyde diethyl acetal, and 2-octanone was attempted by electrolyzing a mixture of acetic acid, ethanol (or tetrahydrofuran and/or acetone), water, and potassium hydroxide. The major products from the electrolysis of enanthaldehyde consisted of 2-octanone, 1-heptanol, 3-methyl-2-octanone, and enanthaldehyde diethyl acetal. Similar products were isolated from the reaction mixture of enanthaldehyde diethyl acetal. The anodic methylation of 2-octanone gave 3-methyl-2-octanone as a major product. Possible mechanisms of the formation of these ketones were discussed.

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