Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
A Theoretical Consideration of the Electron-scavenging Process in Liquid Hydrocarbons. II. Pulse Irradiation
Hideo YamazakiKyoji Shinsaka
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1971 Volume 44 Issue 10 Pages 2611-2615

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Abstract

A mathematical treatment of the electron recombination process is presented on the basis of the extended Smoluchowski equation, which includes the effects of several positive ions as ion cores in a spur and of a scavenger. The equation is reduced to the usual Smoluchowski equation for the geminate recombination in a special case. The time dependence of the electron concentration is obtained using a successive approximation. The results of numerical calculations for various reaction parameters are presented.

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