Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Electron Spin-Spin Interaction in the Multiplet Ground State of Non-planar Methylene Derivatives
Jiro Higuchi
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1971 Volume 44 Issue 10 Pages 2634-2638

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Abstract

The effect of deviation from the planar structure in electron spin-spin interaction has been semiempirically investigated for spin multiplet ground state of radicals with methylene bonds. If these bonds are not coplanar, a significant influence occasionally appears on the values of D and E, while the influence is very small if the relative orientation among the methylene bonds still does not change.

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