Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
Molecular Structure of Dimethyltin Dichloride as Studied by Gas-electron Diffraction
Hideji FujiiMasao Kimura
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1971 Volume 44 Issue 10 Pages 2643-2647

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Abstract

The molecular structure of dimethyltin dichloride was determined by the sector-microphotometer method of electron diffraction to be as follows: rg(Sn–Cl)=2.327±0.003 Å, rg(Sn–C)=2.108±0.007 Å, and rg(C–H)=1.113±0.020 Å, and all the valency angles were near 109.5°. In comparison with the Sn–Cl distances in the series of Sn(CH3)4−nCln, as determined previously by the same method, a regular bond contraction in going from Sn(CH3)3Cl to SnCl4, as pointed out previously by Skinner and Sutton, was ascertained.

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