Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Decomposition of Energized Ethylene Formed in the Photolyses of Alkanes
Yuji OgataKinichi ObiHajime AkimotoIkuzo Tanaka
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1971 Volume 44 Issue 10 Pages 2671-2676

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Abstract

The decomposition and the collisional deactivation of energized ethylene formed in the photolyses of ethane, propane, n-butane, and cyclobutane at 1470 Å have been studied from the change in ethylene and acetylene yields with varying pressures of alkane or nitrogen added as a deactivator. The rate constants of the collisional deactivation and decomposition of energized ethylene were determined from the experimental data. The unimolecular decomposition theory has been applied to energized ethylene, and the results compared with the experimental rate constants.

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