Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
The Polymerization of Silacyclopentene and -pentane Derivatives
Tsunao ArakiDaiyo TerunumaTamio SatoNorio NagaiMitsuharu FuruichiShigeyoshi Nakamura
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1971 Volume 44 Issue 10 Pages 2725-2729

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Abstract

The polymerization of 1,1,3-trimethyl-1-silacyclopentene-3 (I), 1-methyl-, 1-allyl-1,1-diallyl-1-silacyclopentenes and -pentanes with aluminum chloride was carried out. By means of an IR spectroscopic analysis of the resulting polymers, it was established that not only ring opening but also vinyl polymerization due to the C–C double bond occur in this polymerization. Attempts to polymerize I with other catalysts, such as BF3·OEt2, AIBN, KOH, and a Ziegler catalyst, were unsuccessful.

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