Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
p-Nitrophenyl Phosphates as Phosphoryiating Reagents of Alcohols
Kyu-Jang ChongTsujiaki Hata
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1971 Volume 44 Issue 10 Pages 2741-2744

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Abstract

Phosphorylation of alcohols by means of P1,P2-di-p-nitrophenyl pyrophosphate and p-nitrophenyl phosphate was investigated. Alcohols were phosphorylated in almost quantitative yields by use of P1,P2-di-p-nitrophenyl pyrophosphate. It was found that p-nitrophenyl phosphate acts as an effective phosphorylating reagent for alcohols in dry pyridine to give the corresponding alkyl phosphate.

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