Bulletin of the Chemical Society of Japan
Online ISSN : 1348-0634
Print ISSN : 0009-2673
ISSN-L : 0009-2673
γ-Induced Addition of Trialkyltin Hydrides to Unsaturated Esters
Jitsuo TsurugiMasaru IidaRen NakaoTsugio FukumotoNiro Murata
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1971 Volume 44 Issue 3 Pages 777-780

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Abstract

γ-Induced hydrostannation of ethyl acrylate, allyl acetate, and vinyl acetate with triethyltin and tri-n-butyltin hydrides was attempted. The hydrostannation of ethyl acrylate and allyl acetate gave the corresponding adducts in almost quantitative yield. (2-Acetoxyethyl)-tri-n-butyltin expected from hydrostannation of vinyl acetate with tri-n-butyltin hydride could not be isolated. However, NMR and IR spectra indicated the formation of the adduct, which was found to decompose into ethylene and tri-n-butyltin acetate. The decomposition of the adduct was discussed in comparison with other adducts.

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